To prepare this Slow Cooker Chicken and Rice Casserole as a gluten-free dish, ensure that all components—particularly the chicken stock, canned tomatoes, and spices—are certified gluten-free. Use plain basmati rice with no added seasonings, and verify that the packaged chicken thighs do not contain injected sauces or additives containing gluten. When using frozen peas or other vegetables, confirm they are labeled gluten-free and processed in a gluten-safe facility.